Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9760342 | Journal of Power Sources | 2005 | 5 Pages |
Abstract
LiCoO2 thin-film electrodes were prepared by rf-sputtering and sol-gel methods. The prepared thin films contained different amounts of Co3O4 as an impurity depending on the preparation conditions. In situ FT-IR spectroscopic analyses on electrochemical oxidation of ethylene carbonate (EC) and diethyl carbonate (DEC) containing LiClO4 on the LiCoO2 thin-film electrodes were carried out. The electrochemical oxidations of EC and DEC occurred even at 3.8Â V versus Li/Li+ on the fresh LiCoO2. The solvents EC and DEC were oxidized to some compounds with carboxylic groups. In situ FT-IR spectra obtained for the LiCoO2 thin films prepared by different methods were compared each other.
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
Tadashi Matsushita, Kaoru Dokko, Kiyoshi Kanamura,