Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9760397 | Journal of Power Sources | 2005 | 7 Pages |
Abstract
LiNi0.6Co0.4âxMnxO2 (0.15 â¦Â x â¦Â 0.25) cathode materials for lithium-ion batteries are synthesized by calcining a mixture of Ni0.6Co0.4âxMnx(OH)2 and Li2CO3 at 890-950 °C for 15 h in a flowing oxygen atmosphere. The Ni0.6Co0.4âxMnx(OH)2 precursor is obtained by a chemical co-precipitation method at pH = 11. Thermal analysis of the precursor for LiNi0.6Co0.4âxMnxO2 (0.15 â¦Â x â¦Â 0.25) shows that the weight loss is about 30% until the temperature reaches 750 °C. The X-ray diffraction patterns indicate the pure, layered, hexagonal structure of LiNi0.6Co0.4âxMnxO2. Scanning electron micrographs reveal that the morphology of the samples is characterized by larger agglomerates (5-15 μm) of rather small layered particles (around 100 nm). The particle size tends to decrease with increasing Mn content. The electrochemical behaviour of LiNi0.6Co0.4âxMnxO2 powder is examined by using test cells cycled within the voltage range 3-4.3 V at the 0.1 C rate for the first cycle and then at the 0.2 C rate. LiNi0.6Co0.4âxMnxO2 (0.15 â¦Â x â¦Â 0.25) cathode materials exhibit good initial discharge capacity (165-180 mAh gâ1) and a capacity retention of above 95% after 20 cycles. It is demonstrated that LiNixCoyMn1âxâyO2 electrodes are promising candidates for application as cathodes in lithium-ion batteries.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
P.Y. Liao, J.G. Duh, S.R. Sheen,