Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9760444 | Journal of Power Sources | 2005 | 7 Pages |
Abstract
In order to get homogeneous layered oxide Li[Ni1/3Mn1/3Co1/3]O2 as a lithium insertion positive electrode material, we applied carbonate co-precipitation. The oxide compounds were synthesized under different annealing temperature. XRD experiment revealed that the layered Li[Ni1/3Mn1/3Co1/3]O2 material can be synthesized at lower temperature of 750 °C, and the oxidation state of Ni, Mn and Co in the cathode confirmed by XPS were 2+, 4+ and 3+, respectively. SEM observation shows that the synthesized materials have spherical particle morphology and the morphology could be controlled by carbonate co-precipitation method. The cathode synthesized at 800 °C showed small irreversible capacity loss of 10.72% and high discharge capacity of 186.7 mAh gâ1 as well as stable cycling performance in the voltage range 2.8-4.5 VLi/Li+. In spite of difference in specific surface area, rate capability of the samples synthesized in the temperature range 750-900 °C showed similar rate capability and all these cathodes delivered high discharge capacity of over than 143 mAh gâ1 at 2.5 C (450 mA gâ1).
Related Topics
Physical Sciences and Engineering
Chemistry
Electrochemistry
Authors
T.H. Cho, S.M. Park, M. Yoshio, T. Hirai, Y. Hideshima,