Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1254357 | Chinese Chemical Letters | 2016 | 5 Pages |
Abstract
The complexation behaviors of anthracenecarboxylic acid and water-soluble cationic pillararenes have been investigated by 1H NMR, UV–vis and ITC methods. The cationic pillar[6]arene was found to stepwise form 1:1 and 1:2 complexes, having a large K1 and a relatively small K2 values. Photocyclodimerization of AC within the pillar[6]arene improved the yield of the head-to-head photodimers. Up to 4.97 HH/HT ratio has been reached by optimizing the reaction conditions.
Graphical abstractPhotocyclodimerization of anthracenecarboxylic acid within a cationic pillar[6]arene improved the yield of the head-to-head photodimers.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Jian-Chang Gui, Zhi-Qiang Yan, Yuan Peng, Ji-Gao Yi, Da-Yang Zhou, Dan Su, Zhi-Hui Zhong, Guo-Wei Gao, Wan-Hua Wu, Cheng Yang,