Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1254533 | Chinese Chemical Letters | 2012 | 4 Pages |
Abstract
A novel disulphide derivatised deuteroporphyrin 2,7,12,18-tetramethyl-13,17-(propionylaminoethyldithioethyl amino-formylethyl)-29,34-bis-(methoxyformyl)porphyrin (PDTEP, 3) and its cobalt(II) complex (Co(II)PDTEP, 4) were conveniently synthesized. The disulphide functional group of 4 allowed its stable immobilization on gold electrodes. The modified electrode was characterized by IR and confirmed electrochemically and showed good stability and catalytic activity toward the electro-catalyzed reduction of hydrogen peroxide.
Keywords
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Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Shi Chao Xu, Bing Cheng Hu, Wei You Zhou, Cheng Guo Sun, Zu Liang Liu,