Article ID Journal Published Year Pages File Type
1254533 Chinese Chemical Letters 2012 4 Pages PDF
Abstract

A novel disulphide derivatised deuteroporphyrin 2,7,12,18-tetramethyl-13,17-(propionylaminoethyldithioethyl amino-formylethyl)-29,34-bis-(methoxyformyl)porphyrin (PDTEP, 3) and its cobalt(II) complex (Co(II)PDTEP, 4) were conveniently synthesized. The disulphide functional group of 4 allowed its stable immobilization on gold electrodes. The modified electrode was characterized by IR and confirmed electrochemically and showed good stability and catalytic activity toward the electro-catalyzed reduction of hydrogen peroxide.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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