Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1254577 | Chinese Chemical Letters | 2016 | 4 Pages |
A facile preparation method of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes (HNTs), was developed. The characterizations of XRD, TEM, SEM, BET, XRF and FT-IR were used to analyze the structure and properties of the nano-CuO/HNT loaded catalyst. The XRD patterns indicated that the CuO nanoparticles on HNTs were monoclinic phase. The TEM-EDX and SEM images confirmed that most of nano-CuO catalysts with the crystal size of ca. 20 nm were assembled into the hollow nanotube of HNTs. The catalytic performance of the nano-CuO/HNT catalysts was evaluated by using selective oxidation of cyclohexene. The reaction temperature and recycling times were investigated. The results reveal that the nano-CuO/HNT catalysts exhibit an excellent catalytic oxidation performance for selective oxidation of cyclohexene to 2-cyclohexene-1-one.
Graphical abstractThe facile preparation of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes (CuO/HNTs), was developed, which exhibited an excellent catalytic oxidation performance for selective oxidation of cyclohexene to 2-cyclohexene-1-one.Figure optionsDownload full-size imageDownload as PowerPoint slide