| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1254862 | Chinese Chemical Letters | 2014 | 5 Pages |
A coordination polymer formulated as {[Mn2L(N3)4]·2H2O}n(1) [L = 1,4-bis(pyridinil-3-carboxylato)-l,4-dimethylbenzene] was synthesized and structurally and magnetically characterized. The uniform Mn(II) chains with mixed (μ-EO-N3)2(μ-COO) triple bridges (EO = end-on) are linked by L ligands to generate a 2-fold interpenetrating 3D framework. Meanwhile, magnetism analysis reveals antiferromagnetic coupling for 1.
Graphical abstractA coordination polymer formulated as {[Mn2L(N3)4]·2H2O}n (1) [L = 1,4-bis(pyridinil-3-carboxylato)-l,4-dimethylbenzene] was synthesized and characterized. The uniform Mn(II) chains with mixed (μ-EO-N3)2(μ-COO) triple bridges (EO = end-on) are linked by L ligands to generate a 2-fold interpenetrating 3D framework and magnetism analysis reveals dominant antiferromagnetic coupling for 1.Figure optionsDownload full-size imageDownload as PowerPoint slide
