Article ID Journal Published Year Pages File Type
1255146 Chinese Chemical Letters 2012 4 Pages PDF
Abstract

A novel reaction of trimethylsilylated arylacetylenes with sulfonyl chlorides was performed in the presence of silver nitrate or triflate. Conjugated vinyl sulfones as dramatic products were obtained in moderate yields and with Z-selectivity. A free radical mechanism has been proposed to account for the formation of the products.

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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