Article ID Journal Published Year Pages File Type
1255152 Chinese Chemical Letters 2012 4 Pages PDF
Abstract

The linear trienes were obtained in high yields by copper-mediated cycloaddition of 2,5-bis(trimethylsilyl)zirconacyclo-pentadienes with dimethyl acetylenedicarboxylate (DMAD) which can be quantitatively converted to novel asymmetric hexasubstituted cyclohexadienes with high (E)-stereoselectivity. The structure of cyclohexadienes was determined via X-ray analysis.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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