Article ID Journal Published Year Pages File Type
1255541 Chinese Chemical Letters 2009 4 Pages PDF
Abstract

A new 1D infinite neutral chain (Ph3SnO2SeOCH2CH3)n (1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR, elemental analysis, and X-ray single-crystal diffraction. In the compound 1, the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement. It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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