Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1255613 | Chinese Chemical Letters | 2012 | 4 Pages |
Abstract
A new crown ether appended Fe(III) porphyrin complex was prepared by sulfuryl chloride appended benzo-15-crown-5 to the meso position of meso-5, 10, 15, 20-tetra(4-hydrophenyl)porphyrin, and it was applied to catalytic oxidation of cyclohexene with molecular oxygen without reductant, showing a remarkable catalytic activity (conversion is up to 94%) and selectivity for 2-cyclohexen-1-ol (73%).
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Authors
Xiao Dong Li, Yuan Cheng Zhu, Ling Juan Yang,