| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1255729 | Chinese Chemical Letters | 2011 | 4 Pages |
Abstract
The hydration of phenylacetylene in near-critical water, assisted with additives (NaHSO4, ZnCl2, FeCl3), has been successfully conducted with temperature and residence time ranges of 220–300 °C and 60–180 min, respectively. The results showed the catalytic ability is FeCl3 > ZnCl2 > NaHSO4. The maximum yield of product acetophenone was 96.68% at 260 °C, 120 min. Based on the results found, a possible mechanism of hydration of phenylacetylene in near-critical water was proposed.
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Authors
Shuang Li, Yong Juan Chang, Yu Wang, Li Yi Dai,