Article ID Journal Published Year Pages File Type
1257457 Chinese Chemical Letters 2012 4 Pages PDF
Abstract

An effective method for the synthesis of vinyl thioethers through the conjugate addition of ethanethiol to electron-deficient alkynes promoted by BF3·Et2O has been developed. Electron-deficient internal alkynes react with ethanethiol in this system to yield mainly Z-isomer of vinyl thioether adducts, while electron-deficient terminal alkynes afford mainly E-isomer of vinyl thioether adducts.

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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