Article ID Journal Published Year Pages File Type
1257462 Chinese Chemical Letters 2012 4 Pages PDF
Abstract

Ring opening of aziridine with dialkyl amine took place readily in the presence of catalytic amounts of tri-n-butylphosphane (10 mol%) in the mixture of CH3CN/H2O (10:1), giving corresponding vicinal diamines in mediate to high yields (58–95%) with good regioselectivitie, while aromatic secondary amine could not react under the same conditions. Tri-n-butylphosphane exhibited different catalytic selectivity to amines from Lewis acid catalysts.

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Physical Sciences and Engineering Chemistry Chemistry (General)
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