Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1257492 | Chinese Chemical Letters | 2012 | 4 Pages |
Abstract
An effective and environmentally benign benzylic oxidation for transition of alkylarenes into the corresponding carbonyl compounds was reported. Alkylarenes were mixed and stirred with potassium bromide, m-chloroperbenzoic acid and a catalytic amount of iodobenzene in water at 60 °C for several hours, a series of the corresponding carbonyl compounds was obtained in moderate to good yields. In the reaction, iodobenzene was first oxidized by m-chloroperbenzoic acid into the hypervalent iodine intermediate which then reacted with potassium bromide to form the key radical initiator for the benzylic oxidation.
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Authors
Yuan Xu, Jian Tao Hu, Jie Yan,