Article ID Journal Published Year Pages File Type
1258072 Chinese Chemical Letters 2009 4 Pages PDF
Abstract

A convenient and facile one-pot synthesis of stable phosphorus ylides and 1,4-diionic organophosphorus compounds is reported by the reaction of triphenylphosphine, dialkylacetylenedicarboxylates and N–H, C–H or S–H acids in the presence of polyethyleneglycol (PEG), β-cyclodextrin (β-CD), glycerine (Gly) or ethyleneglycol (EG) in water. This methodology is of interest due to the use of water as a solvent, thus minimizing the cost operational hazards, and environmental pollution.

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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