| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1258121 | Chinese Chemical Letters | 2010 | 4 Pages |
Abstract
Comparison in electron transfer (ET) processes from decamethyferrocene (DMFe) in nitrobenzene (NB) to ferric ion in aqueous phase was investigated for the first time by the scanning electrochemical microscopy (SECM). As compared with the system of Fe(CN)63−–DMFe, the ET rate obtained from Fe3+–DMFe was lower in spite of larger driving force, which may arise from the effect of reorganization energy. Otherwise, the effect of common ion on rate constants was also probed and results suggested additional complexity of the ET mechanism between Fe(CN)63− and DMFe.
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Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Xiao Quan Lu, Jun Ying Ma, Xiu Hui Liu, Cun Wu Dong, Wen Ting Wang,