Article ID Journal Published Year Pages File Type
1258162 Chinese Chemical Letters 2009 4 Pages PDF
Abstract

Two novel C-nor-B-homo aconane-type diterpenes 4 and 5, featuring a unique eight-membered ring system, were obtained by the treatment of C-nor-C19-diterpenoid alkaloid 3 with HNO2 in 8% and 21% yields, respectively. Structures of these two compounds were established based on the combination of spectroscopic data, including HRESIMS, 1D and 2D NMR data. A plausible mechanism for the formation of 4 and 5 is also presented.

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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