| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1258662 | Chinese Chemical Letters | 2007 | 4 Pages |
Abstract
Silylated Ti-grafted hexagonal mesoporous silica (HMS) catalyst was prepared by the chemical vapor deposition (CVD) using TiCl4 as titanium source and hexamethyldisilazane (HMDSZ) as silylating agent. The samples were characterized by XRD, N2-adsorption, FTIR, 29Si NMR, DR UV–vis, and evaluated by epoxidation of styrene, propylene, cyclohexene, and 1-hexene with cumene hydroperoxide (CHP) as oxidant, respectively. It is revealed that the catalyst possesses typical mesoporous structure, high hydrophobicity and highly dispersed tetracoordinated titanium sites and hence exhibits excellent performance in epoxidation of olefins.
Keywords
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Physical Sciences and Engineering
Chemistry
Chemistry (General)
Authors
Xue Feng Li, Huan Xin Gao, Guo Jie Jin, Lin Ding, Lu Chen, Hong Yun Yang, Xin He, Qing Ling Chen,