The problem of cold starts: A closer look at mobile source emissions levels

While the phenomenon of excess vehicle emissions from cold-start conditions is well known, the magnitude and duration of this phenomenon is often unclear due to the complex chemical processes involved and uncertainty in the literature on this subject. This paper synthesizes key findings regarding the influence of ambient and engine temperatures on light-duty vehicle (LDV) emissions. Existing literature, as well as analytical tools like the U.S. Environmental Protection Agency's Motor Vehicle Emission Simulator (MOVES), indicate that while total vehicle emissions have dropped significantly in recent years, those associated with cold starts can still constitute up to 80% for some pollutant species. Starting emissions are consistently found to make up a high proportion of total transportation-related methane (CH4), nitrous oxide (N2O), and volatile organic compounds (VOCs). After 3-4 min of vehicle operation, both the engine coolant and the catalytic converter have generally warmed, and emissions are significantly lower. This effect lasts roughly 45 min after the engine is shut off, though the cooling rate depends greatly on the emission species and ambient temperature. Electrically (pre-)heated catalysts, using the bigger batteries available on hybrid drivetrains and plug-in vehicles, may be the most cost-effective technology to bring down a sizable share of mobile source emissions. Trip chaining (to keep engines warm) and shifting to non-motorized modes for shorter trips, where the cold start can dominate emissions, are also valuable tactics.