Keywords: C-S cleavage; Group 9 metals; Cyclometalation; X-ray crystallography;
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Keywords: Cyclometalation; C-H activation; N-donor ligands; Transition metals; Catalysis;
Keywords: Iridium; Cyclotron; Cyclometalation; Osmium; Irradiation;
Keywords: Sensor; Cyclometalation; Five-membered ring; Photoluminescence; Phenylpyridine;
Keywords: Vinylic C–Cl bond activation; Cycloalkenyl aldehyde; Trimethylphosphine; Cyclometalation
Keywords: Palladium; Cyclometalation; C–H bond activation; Coordination; Regioselectivity
Keywords: Ligand design; Rare earth; Scandium; Yttrium; Phosphinimine; Cyclometalation;
Keywords: Cyclometalation; Five-membered ring; Cisplatin; Anticancer agent; Cytotoxicity
Substituent effects on cyclometalation: N-benzylideneanilines
Keywords: Photoelectron spectroscopy; Cyclometalation; N-benzylideneanilines;
Density functional theory study on ruthenium dyes and dye@TiO2 assemblies for dye sensitized solar cell applications
Keywords: Cyclometalation; Density functional theory; Dye sensitized solar cell; Ru-sensitizers; Solvent effect; Thiocyanate-free;
Red-emitting cyclometalated platinum(II) complexes with imidazolyl phenanthrolines: Synthesis and photophysical properties
Keywords: Cyclometalation; Platinum; Phenanthroline; Luminescence; Electrochemistry; TDDFT;
Mono and dinuclear bis(ortho-tolyl)platinum(II) compounds containing diethyl sulfide ligands: Synthesis, DFT studies and use as precursors in cycloplatination reactions
Keywords: Bis(ortho-tolyl)platinum(II) compounds; Dimerization; DFT studies; Cyclometalation; Imine ligands;
[Au(pyb-H)(mnt)]: A novel gold(III) 1,2-dithiolene cyclometalated complex with antimicrobial activity (pyb-H = C-deprotonated 2-benzylpyridine; mnt = 1,2-dicyanoethene-1,2-dithiolate)
Keywords: Gold; Cyclometalation; Dithiolene; Biofilm; Antimicrobic; DFT;
Exploring the C^N^C theme: Synthesis and biological properties of tridentate cyclometalated gold(III) complexes
Keywords: Gold(III) complexes; Cyclometalation; Anticancer agents; Thioredoxin reductase; Thiols;
Ruthenium(II) DMSO complexes with CËC* cyclometalated phenylimidazol NHC ligands
Keywords: Ruthenium(II); NHC; Cyclometalation; DMSO; Heteroleptic; DFT;
Synthesis, structure and reactivity of scandium bis(trimethylsilyl)amido derivatives
Keywords: Scandium; Rare earth; Bis(trimethylsilyl)amido; Cyclometalation; Starting material
Formation of 5-membered metallacycles at iPrPCPIr by C–H, O–H, and C–CO bond cleavage
Keywords: Iridium; Pincer ligand; PCP pincer; Cyclometalation; Metallacycle
Impact of cyclometalated ruthenium(II) complexes on lactate dehydrogenase activity and cytotoxicity in gastric and colon cancer cells
Keywords: Ruthenium; Cyclometalation; Lactate dehydrogenase; Cytotoxicity; Molecular docking; Enzyme inhibition
Microwave-induced dppm ligand substitution in triosmium clusters: Structural and DFT evaluation of Os3 clusters containing multiply activated dppm ligands through cyclometalation, ortho metalation, and PC bond cleavage
Keywords: Triosmium carbonyl cluster; Diphosphine ligands; Ortho metalation; Cyclometalation; Microwave synthesis; CH bond activation
Resisting B–H oxidative addition: The divergent reactivity of the o-carborane and carba-closo-dodecaborate ligand substituents
Keywords: Carborane anion; Carborane ligand; Cyclometalation; Carboranyl phosphine; Boron cluster
A luminescent Pt-POCN pincer complex via direct cyclometalation
Keywords: Cyclometalation; Platinum; Mixed-donor; Pincer complex; Crystal structure; Emission spectroscopy
Role of anagostic interactions in cycloplatination of telluroethers: Synthesis and structural characterization
Keywords: Platinum; Telluroether; Cyclometalation; Anagostic interaction; NMR; X-ray
Quadruple cyclometalation of a diphosphine-dicarboxamide ligand at platinum(II)
Keywords: Cyclometalation; Platinum; Phosphine-carboxamide; Pincer ligand;
(C∧C*)-cyclometalated platinum(II) imidazo[1,5-a]pyridine NHC complexes – Synthesis and characterization
Keywords: N-heterocyclic carbene; Platinum(II); Cyclometalation; DFT calculations; Solid-state structure
Cyclometalated mono and dinuclear rhodium(III) and iridium(III) complexes with imidazolyl phenanthrolines: Synthesis and, photophysical and electrochemical characterization
Keywords: Cyclometalation; Iridium; Rhodium; Fluorescence; Electrochemistry
Synthesis and characterisation of new PCsp3P-supported nickel complexes
Keywords: Aliphatic pincer complexes; PCP pincer ligands; Nickel; Cyclometalation; Coordination
A glance at the reactivity of osma(II)cycles [Os(C–N)x(bpy)3 − x]m + (x = 0–3) Covering a 1.8 V Potential Range toward Peroxidase through Monte Carlo Simulations (−C–N = o-2-phenylpyridinato, bpy = 2,2′-bipyridine)
Keywords: Cyclometalation; Osmium; Peroxidase; Electron transfer; Monte Carlo simulations
Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cpâ(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium
Keywords: N-heterocyclic carbene ring-opening; Anionic carbene complexes; C-H activation; Cyclometalation; Silylene complexes;
Tuning the photophysical and electrochemical properties of iridium(III) 2-aryl-1-phenylbenzimidazole complexes
Keywords: Iridium(III) complexes; Benzimidazole; Cyclometalation; Electrochemical studies; DFT calculation; Absorption spectra
Synthesis of [Ru3(CO)9(μ-dppf){P(C4H3E)3}] (E = O, S) and thermally induced cyclometalation to form [(μ-H)Ru3(CO)7(μ-dppf){μ3-(C4H3E)2P(C4H2E)}] (dppf = 1,1′-bis(diphenylphosphino)ferrocene)
Keywords: Triruthenium; Trifurylphosphine; Trithienylphosphine; Cyclometalation; Diphosphine; DFT
Enhancement of smectic C mesophase stability by using branched alkyl chains in the auxiliary ligands of luminescent Pt(II) and Pd(II) complexes
Keywords: Cyclometalation; Liquid crystals; Platinum(II); Palladium(II); Luminescence; N-Benzoylthiourea
How to blue-shift phosphorescence color of iridium(III) complexes
Keywords: Iridium; 1,10-Phenanthroline; Fluorocarbon; Complex; Cyclometalation; Phosphorescence;
Phosphorescence of iridium(III) complexes with 2-(2-pyridyl)-1,3,4-oxadiazoles
Keywords: Iridium; 1,3,4-Oxadiazole; Ligand; Complex; Cyclometalation; Phosphorescence;
Steric hindrance at metal centre quenches green phosphorescence of cationic iridium(III) complexes with 1-(2-pyridyl)-pyrazoles
Keywords: Pyrazole; Ligand; Iridium; Complex; Cyclometalation; Phosphorescence
Pd–C bond formation with the indole ring in palladium complexes of N,N,O-donor ligands. Effect of the nitrogen donor properties
Keywords: Pd(II) complexes; Indole; Cyclometalation; Pd(II)–indole bond; Nitrogen donors
CˆC*-cyclometalated platinum(II) complexes with trifluoromethyl-acetylacetonate ligands – Synthesis and electronic effects
Keywords: Platinum(II)–NHC complexes; Cyclometalation; Electronic effects; DFT calculations
Biscyclometalated platinum complexes with thiophene ligands
Keywords: Cyclometalation; Platinum; Thiophene; Emission; DFT
Charged cyclometalated iridium(III) complexes that have large electrochemical gap
Keywords: Iridium; Cyclometalation; Complex; Pyrazole; Electrochemistry
Phosphorescent cationic iridium(III) complexes with cyclometalating 1H-indazole and 2H-[1,2,3]-triazole ligands
Keywords: Iridium; Indazole; [1,2,3]-Triazole; Cyclometalation; Complex; Phosphorescence
An orthomanganation route to 2-substituted derivatives of N-methyl-1,8-naphthalimide
Keywords: Naphthalimide; Cyclometalation; Manganese carbonyl; X-ray crystal structure; Alkyne
Cyclometalated phenylquinoline rhodium complexes as protein kinase inhibitors
Keywords: Rhodium; Cyclometalation; Kinase inhibitors; Chiral ligand; Asymmetric synthesis;
Iridium phosphine abnormal N-heterocyclic carbene complexes in catalytic hydrogen transfer reactions
Keywords: Abnormal N-heterocylic carbene; Cyclometalation; Iiridium hydride; Hydrogen-borrowing; Dehydrogenation;
C–H activation of benzene by platinum(II) complexes with cyclometalated phosphine ligands
Keywords: Platinum complexes; Cyclometalation; Phosphine; C–H activation
Synthesis, characterization, and cyclometalation studies of benzo[1,2-h: 5,4-h′]diquinolines with palladium and platinum
Keywords: Pincer ligands; Benzodiquinolines; Cyclometalation; Heck reaction
On the Activation of Chloromethanes by Cyclometalated [Pt(bipy - H)]+ in the Gas Phase: A Mechanistic Study
Keywords: 2,2â²-bipyridine; Bond activation; Cyclometalation; Platinum complexes; Chloromethanes;
A cyclometalated diplatinum complex containing 1,1′-bis(diphenylphosphino)ferrocene as spacer ligand: Antitumor study
Keywords: Organoplatinum; Cyclometalation; Phosphine ligand; Antitumor agent; NMRC^N, deprotonated 2-phenylpyridine; COSY, Correlation Spectroscopy; dmso, dimethylsulfoxide; dppf, 1,1′-bis(diphenylphosphino)ferrocene; HMBC, Heteronuclear Multiple Bond Correlation;
Substitution reactions involving cyclometalated platinum(II) complexes: Kinetic investigations
Keywords: Cyclometalation; Organoplatinum; Substitution; Kinetics; Mechanism
Syntheses of platinum(II) complexes of cyclo-octenyl group and isolation of a self-assembled oxo-bridged macrocyclic complex [Pt4(Spy)4(C8H12-O-C8H12)2]
Keywords: Platinum; 8-Methoxy-cyclooct-4-ene-1-yl; Cyclometalation; Pyridine-2-thiolate
Concentration-dependent palladium(II)–indole bond formation in complexes with a 2N-donor ligand containing an indole moiety: Synthesis, characterization, and reaction analysis
Keywords: Pd(II) complexes; Indole; Cyclometalation; Pd(II)–indole bond; Concentration dependent change
Cyclometalated complexes derived from calix[4]arene bisphosphites and their catalytic applications in cross-coupling reactions
Keywords: Calix[4]arene bisphosphites; Palladium and platinum dichloride complexes; Cyclometalation; Heck and Suzuki coupling reactions