Liquid gadolinium corrosion study of TaC coating on tantalum

Spectroscopic information of gadolinium isotopes is necessary to exploit the full potential of various isotopes in nuclear and medical applications. Container materials to handle liquid gadolinium during spectroscopic studies is an important aspect. Tantalum carbide (TaC) has excellent stability and also exhibits superior resistance to attack by various reactive actinide metals at high temperature for long durations. Tantalum crucibles with TaC coating were prepared and tested for compatibility against liquid gadolinium at 1673 K upto 14 h in vacuum. Optical microscopy and SEM/EDS investigations were done to evaluate the micro structural features of the coating and the liquid gadolinium attack. Experimental results show that TaC coating exhibits excellent corrosion resistance against liquid gadolinium at 1673 K.