کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10263022 | 457085 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modeling the reaction of gaseous HCl with CaO in fluidized bed
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An integrated mathematical model is developed to evaluate the performance of the reaction of gaseous HCl and CaO in fluidized bed. The model considers initial pore size distribution of solid reactant, pore structure change and attrition caused by particles movement. Bethe network is used to describe the pore space topology, and the percolation theory is used to determine the accessible reaction surface area of the sorbent particles and the effective diffusion coefficient of gaseous HCl. This model prediction accounts for the diffusion of HCl in shrinking pore space as well as in product layer, and clearly demonstrates the increasing diffusion resistance and the isolation of partially reacted pores causing incomplete conversion of solid. The model shows excellent agreement with the experimental data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 61, Issue 16, August 2006, Pages 5468-5475
Journal: Chemical Engineering Science - Volume 61, Issue 16, August 2006, Pages 5468-5475
نویسندگان
Shiyuan Li, Rushan Bie,