کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10377976 | 880747 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Surface potential at the hematite-water interface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Construction of a metal oxide electrode enabling measurement of surface potential is described. The electrode was made using a hematite monocrystal, which avoids the problems arising from the possible porosity of the oxide layer. The potential of this electrode was measured as a function of pH. The hematite electrode provides reproducible results, especially in the acidic region. Surface potentials were calculated from electrode potentials using the electrokinetic isoelectric point. The slope of surface potential with respect to pH was found to be lower than the Nernstian, especially in the basic region. The effect was more pronounced at higher ionic strengths. It was shown how the measurement of surface potential can help to interpret the equilibrium data and evaluate the choice of a theoretical model describing the interfacial equilibrium at the metal oxide-water interface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 286, Issue 2, 15 June 2005, Pages 610-614
Journal: Journal of Colloid and Interface Science - Volume 286, Issue 2, 15 June 2005, Pages 610-614
نویسندگان
N. Kallay, Z. DojnoviÄ, A. Äop,