کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10624510 | 989594 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-surface area co-electrospun TiO2 nanowires fabricated using shrinkage of polyvinylpyrrolidone for improved photovoltaic performance
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Surface-roughened TiO2 nanowires (NWs) were fabricated using co-electrospinning with different molecular weights of polyvinylpyrrolidone (PVP) polymer: low molecular weight PVP (Mw=360,000Â g/mol) for the core region and high molecular weight PVP (Mw=1,300,000Â g/mol) for the shell region. Together with the formation mechanism, their surface property, morphology, crystal structure, and photovoltaic performance were studied. The results showed that the surface-roughened TiO2 NWs had an enhanced specific surface area because of the rough NW surface compared to the pure TiO2 NWs. As a result, the short-circuit current density (8.94Â mA/cm2) of DSSCs fabricated with the surface-roughened TiO2 NWs is higher than that (5.88Â mA/cm2) of the pure TiO2 NWs. Therefore, the photoconversion efficiency of the surface-roughened TiO2 NWs exhibited a high value of ~3.63% compared to that of the pure TiO2 NWs. This phenomenon can be explained by the enhancement of short-circuit current density by an increased dye adsorption; this is because of the increased specific surface area induced by the NW shrinkage due to the different thermal decomposition behavior of PVP depending on the different molecular weights of PVP.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 42, Issue 1, Part B, January 2016, Pages 1666-1671
Journal: Ceramics International - Volume 42, Issue 1, Part B, January 2016, Pages 1666-1671
نویسندگان
Bon-Ryul Koo, HyeLan An, Hyo-Jin Ahn,