کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10625674 | 989632 | 2013 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of CaCu3Ti4O12 ceramics with low dielectric loss and giant dielectric constant by the sol-gel technique
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
CaCu3Ti4O12 precursor powders were synthesized by the sol-gel process. The optimized processing parameters for the synthesis of precursor powders were as follows: the Ti concentration was 0.60 mol/L, the pH value of the sol was 1.58, and the aging time of the sol was 6 h. After sintering at 1100 °C for 15 h, the CCTO ceramics with the highest density and fine-grained microstructure were obtained, exhibiting outstanding dielectric properties: εâ²â3.50Ã104 and tan δ=0.014 (at 1 kHz). The low dielectric loss was attributed to the highest grain boundary resistance which significantly reduced the leakage current across grain boundaries. A broad dielectric relaxation peak was observed around 300 °C. The complex impedance spectroscopy analysis suggested that the obtained CaCu3Ti4O12 ceramics were electrically heterogeneous, consisting of semiconducting grains and insulating grain boundaries. The calculated grain boundary resistance and grain resistance were 0.87 MΩ and 3.50 Ω, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 39, Issue 7, September 2013, Pages 7879-7889
Journal: Ceramics International - Volume 39, Issue 7, September 2013, Pages 7879-7889
نویسندگان
Yanyan Li, Pengfei Liang, Xiaolian Chao, Zupei Yang,