کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10632011 | 992377 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and structural refinement of polycrystalline ceramic powder Pr0.1Ca0.9TiO3
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Perovskite structure-based ceramic precursors have a characteristic property of substitution in the 'A' site of the ABO3 structure. This makes them a potential material for nuclear waste management in synthetic rock (Synroc) technology. In order to simulate the mechanism of rare earth fixation in perovskite, PrxCa1âxTiO3 (where x = 0.1) has been synthesized through ceramic route by taking calculated quantities of oxides of Ca, Ti and Pr as starting materials. The ceramic phase has been characterized by its powder diffraction pattern. The Rietveld analysis of the X-ray diffraction data has been carried out using GSAS software to achieve the convergence which gives the Rp = 5.74% and Rwp = 8.17%. The (h, k, l) values for different lattice planes have been calculated. The praseodymium substituted perovskite crystallizes in orthorhombic symmetry with space group: Pbnm, Z = 4. The unit cell parameters at room temperature are a = 5.39609(31) Ã
, b = 5.44869(30) Ã
and c = 7.6565(5) Ã
. The calculated and observed values of the corresponding intensities, 2θ and density of the polycrystalline powder show good agreement. GSAS-based calculation for bond distances TiO, CaO and bond angles OTiO, OCaO has been reported.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 40, Issue 5, 18 May 2005, Pages 731-741
Journal: Materials Research Bulletin - Volume 40, Issue 5, 18 May 2005, Pages 731-741
نویسندگان
O.P. Shrivastava, Narendra Kumar, I.B. Sharma,