کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11029574 | 1646486 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption study of thin films of terephthalic acid and substituted benzoic acids on HOPG studied by Metastable Induced Electron Spectroscopy and Ultraviolet Photoelectron Spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The adsorption behavior of thin films of 4-alkoxybenzoic acids (with either hydroxy-, methoxy-, propoxy-, pentoxy- and decoxy-chains) and terephthalic acid, evaporated on a Highly Oriented Pyrolytic Graphite (HOPG) surface was studied. The orientation of the molecules was characterized by Metastable Induced Electron Spectroscopy (MIES) and Ultraviolet Photoelectron Spectroscopy (UPS(HeI)). On HOPG the 4-alkoxybenzoic acids and the terephthalic acid show a layer like growth at the beginning. Since the MIE spectra for the molecules on HOPG show all molecular orbitals, especially the Ï orbitals of the phenyl ring, a flat laying orientation on the graphite surface is assumed. The only exception is observed for 4-decoxy-benzoic acid. After a coverage of approximately 1 monolayer (ML) the spectrum is dominated by the spectral features of the alkyl structures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 229, December 2018, Pages 26-32
Journal: Journal of Electron Spectroscopy and Related Phenomena - Volume 229, December 2018, Pages 26-32
نویسندگان
Marcel Marschewski, Harun TaÅ, Christian Otto, Wolfgang Maus-Friedrichs, Andreas Schmidt, Oliver Höfft,