کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1207497 | 1493715 | 2008 | 8 صفحه PDF | دانلود رایگان |
Quantitative information of alkylated PAH is frequently used in forensic investigations to characterize petroleum releases and fate in the environment. Interference from a complex matrix often obviates target compound quantitation. Using single ion SIM or a single mass spectral pattern to analyze these homologs should result in either over- or underestimating their concentration. To confirm this hypothesis, a library of C1–C4 alkylated PAH fragmentation patterns were made from automated sequential two-dimensional GC–GC/MS data and the Ion Signature deconvolution software. Based on these patterns, 1D GC/MS data was compared using single ion extraction and one fragmentation pattern per homolog against data obtained from those peaks whose scans met the spectral deconvolution criteria. Significant overestimation occurs when a single ion is used to extract peak signal for C4-naphthalene, C1-fluorene, and the C1- to C3-dibenzothiophenes. In contrast, C2-naphthalene, C2-fluorene, C3-phenanthrene, and C1-dibenzothiophene were underestimated by >50% when one fragmentation pattern per homolog was used. The Ion Signature deconvolution software makes it easy to interpret mass spectrometry data, especially in complex environmental samples like diesel fuel.
Journal: Journal of Chromatography A - Volume 1205, Issues 1–2, 26 September 2008, Pages 109–116