کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1231165 1495273 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ketocyanine dyes as sensors for proticity and pH of a medium
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Ketocyanine dyes as sensors for proticity and pH of a medium
چکیده انگلیسی

Photophysical properties of two structurally similar ketocyanine dyes have been studied in aprotic + protic (dioxane + water, tetrahydrofuran + water) and protic + protic (methanol + water) solvent mixtures. The observed photophysical properties of these dyes show different trends with an increase in solvent polarity (in the ET(30) scale) in aprotic and protic media. The H-bonding at the carbonyl centres of the dyes in the excited state presumably plays a role in modifying the emitting state and hence the photophysical properties show similar trend in a protic solvent or in a mixed aprotic + protic solvent at higher percentage of the later. Thus the dyes are supposed to act as useful probes for studying H-bonding ability of a medium. Absorption and fluorescence spectral characteristics of these dyes have been found to get modified in the presence of strong acid. The presence of H+ ions persists the dyes to exist in equilibrium with the protonated forms having different absorption and fluorescence characteristics. Reversible change of the equilibrium with pH of the medium makes the dyes, particularly the symmetric one, good probes for indicating the pH of the medium.

Figure optionsDownload as PowerPoint slideHighlights
► Optical response of two ketocyanine dyes has been studied in mixed binary solvent.
► Photophysics of the dye in protic media differs from that in aprotic media.
► These dyes can act as pH and proticity sensors.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 95, September 2012, Pages 569–575
نویسندگان
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