کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1234605 | 968832 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nickel(II) thiohydrazide and thiodiamine complexes: Synthesis, characterization, antibacterial, antifungal and thermal studies
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Nickel(II) complexes of type [Ni(L)2Cl2] and [Ni(L)2(OCOCH3)2], where L = N,N-diphenyl-N-thiohydrazide (L1) and (N,N-diphenyl-N-thio)-1,3-propanediamine (L2), have been synthesized. The thiodiamines coordinate as a bidentate N–S ligand. The synthesized nickel(II) complexes of the thiodiamines were characterized by elemental analysis, IR, mass, electronic and 1H NMR spectroscopic and TG/DTA studies. Various kinetic and thermodynamic parameters like order of reaction (n), activation energy (Ea), apparent activation entropy (S#) and heat of reaction (ΔH) have also been carried out for one complex. These complexes were also screened for in vitro antifungal and in vitro antibacterial activities and significant activity have been found.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 69, Issue 3, March 2008, Pages 842–848
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 69, Issue 3, March 2008, Pages 842–848
نویسندگان
A.K. Mishra, N.K. Kaushik,