کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1251132 | 970889 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Low-temperature infrared spectra and hydrogen bonding in polycrystalline dl-serine and deuterated derivatives
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The FT-IR spectra of polycrystalline dl-serine [α-amino-β-hydroxypropionic acid; HO-CH2-CH(NH3)+-COOâ] and isotopically substituted [ND/ODAlcohol (<10% and >90% D); CD2 (>98% D)] dl-serine were recorded in the range 4000-500 cmâ1 in the temperature range 300-10 K, and fully assigned. The isotopic-doping/low-temperature methodology, which allows for decoupling of individual proton vibrational modes from the crystal bulk vibrations, was used to estimate the energies of the different H-bonds present in dl-serine crystal. To this end, the frequency shifts observed in both the NH/OH stretching and out-of-plane bending spectral regions (relatively to reference values for these vibrations in non-hydrogen-bonded dl-serine molecules) were used, together with previously developed empirical correlations. The results are compared with available structural data on this amino acid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 41, Issue 1, 30 May 2006, Pages 73-82
Journal: Vibrational Spectroscopy - Volume 41, Issue 1, 30 May 2006, Pages 73-82
نویسندگان
S. Jarmelo, I. Reva, M. Rozenberg, P.R. Carey, R. Fausto,