Effects of grain size and dislocation density on the susceptibility to high-pressure hydrogen environment embrittlement of high-strength low-alloy steels

The tensile properties of several high-strength low-alloy steels in a 45 MPa hydrogen atmosphere at ambient temperature were examined with respect to the effects of grain size and dislocation density on hydrogen environment embrittlement. Grain size was measured using an optical microscope and dislocation density was determined by X-ray diffractometry. Both grain refinement and a reduction in dislocation density are effective in reducing the susceptibility to embrittlement. The steel that has high dislocation density or large grain size inclines to show a smooth intergranular fracture surface. Given only the grain size and dislocation density, a simple approximation of the embrittlement property of high-strength steel could be obtained. This method could be useful in selecting candidate materials in advance of the mechanical tests in high-pressure hydrogen gas.

► Grain refinement suppresses hydrogen environment embrittlement.
► Reduction in dislocation density also suppresses hydrogen environment embrittlement.
► Grain size and dislocation density can make a useful map for embrittlement evaluation.