کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1301535 1498934 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pseudo-isomeric zinc/copper coordination polymers based on 3-(2-pyridyl)pyrazole-5-carboxylic acid
ترجمه فارسی عنوان
پلیمرهای همگن سازی روی / مس پلیس بر اساس 3- (2-پیریدیل) پریازول 5-کربوکسیلیک اسید
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی


• 3-(2-Pyridyl)pyrazole-5-carboxylate and Zn or Cu ions form 2D MOFs.
• The two MOFs have pseudo-isomeric crystal structures.
• The Zn MOF shows increased fluorescence compared to free ligand.
• Cu MOF has antiferromagnetic intra-dimer and ferromagnetic inter-dimer exchanges.

Reaction of 3-(2-pyridyl)pyrazole-5-carboxylic acid (H2L) with Zn(II) or Cu(II) perchlorate yielded [ZnL]n (1) and [CuL]n (2) with similar composition. The ligand L2 − adopts the same μ3κ5 coordination mode. The Zn(II) and Cu(II) atom takes square pyramid coordination polyhedron with some discrepancy. Bigger difference in the dimeric secondary building blocks leads to distinct two-dimensional metal–organic frameworks. The Zn(II) complex fluoresces stronger than the free ligand. The Cu(II) polymer displays strong antiferromagnetic intra-dimer exchange and ferromagnetic inter-dimer exchange.

2D MOFs formed by 3-(2-pyridyl)pyrazole-5-carboxylate and Zn(II) or Cu(II) have similar compositions and coordination modes, but significant discrepancy in the dimeric secondary building blocks causes different coordination networks.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 56, June 2015, Pages 120–124
نویسندگان
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