کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1301735 | 1498919 | 2016 | 4 صفحه PDF | دانلود رایگان |
• Dinuclear Ag(I) complexes bearing the P ∩ N ligand 2-diphenylphosphino-6-methylpyridine have been prepared.
• The complex have the generic formula [Ag2(P ∩ N)3(NCR)](BF4)2 (R = Me, Et, Ph).
• The crystal structures were determined.
• The nitrile ligands can be easily exchanged by re-crystallisation in the respective organic nitrile.
We have prepared three silver(I) complexes of the type [Ag2(P ∩ N)3(NCR)](BF4)2 with (R = Me, Et, Ph). The crystal structures of the complexes were determined. The nitrile ligands can be easily exchanged by re-crystallisation in the respective nitrile. The luminescence properties were also investigated.
We have prepared three silver(I) complexes of the type [Ag2(P ∩ N)3(NCR)](BF4)2 with (R = Me, Et, Ph). The crystal structures of the complexes were determined. The nitrile ligands can be easily exchanged by re-crystallisation in the respective nitrile. The luminescence properties were also investigated.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 71, September 2016, Pages 105–108