کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1304442 | 974829 | 2009 | 4 صفحه PDF | دانلود رایگان |
By control of mixed organic ligands with different geometries, three unusual 4d–4f heterometallic coordination polymers, [AgLn(nic)2(ox)] · 2H2O [Ln = Eu (1); Dy (2); Ho (3)] [nic = nicotinate; ox = oxalate] have been synthesized under hydrothermal reaction. Three structures represent 3D open heterometallic coordination frameworks that are constructed from rare zigzag lanthanide-ox-silver chains and nic linkers. Furthermore, the luminescent property of complex 1 was discussed.
Three unusual 3D 4d–4f coordination polymer, [AgLn(nic)2(ox)] · 2H2O [Ln = Eu (1); Dy (2); Ho (3)] [nic = nicotinate; ox = oxalate] were successfully synthesized. All three structures exhibit same 3D open heterometallic coordination frameworks that are constructed from rare zigzag lanthanide-ox-silver chains and nic linkers.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 3, March 2009, Pages 204–207