کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1304446 | 974829 | 2009 | 4 صفحه PDF | دانلود رایگان |
A new mixed-valence hexadecavanadate cluster compound, (Me2NH2)4[H6V16O42(SO4)] · 8H2O (1), has been synthesized via an efficient method in organic media. The hollow cluster shell of 1, with a sulfate ion locating in its centre, exhibits four large eight-membered –O–V–O–V– rings on its surface, which makes the cluster into a half-open structure distinguished from the common hollow clusters built up with closed surfaces. The intense blue luminescence of 1 in solution state is scarcely reported for the polyoxometalate clusters.
A new mixed-valence hexadecavanadate cluster compound, (Me2NH2)4[H6V16O42(SO4)] · 8H2O (1), has been synthesized via efficient method in organic media. The hollow cluster shell of 1, with a sulfate ion locating in its centre, exhibits four large eight-membered –O–V–O–V– rings on its surface, which makes the cluster into a half-open structure.Figure optionsDownload as PowerPoint slide
Journal: Inorganic Chemistry Communications - Volume 12, Issue 3, March 2009, Pages 219–222