کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1312045 | 1499150 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of fluorophenyl carbonyl cobalt(I) complexes and decarbonylation of 2,4,5-trifluorobenzaldehyde catalyzed by CoMe(PMe3)4
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
Three fluorophenyl carbonyl cobalt(I) complexes PhF(PMe3)3Co(CO) (1-3) were synthesized by the reaction of fluoro-benzaldehydes with CoMe(PMe3)4 via C-H bond activation and decarbonylation reaction. The chemical properties of complexes 1 and 3 were studied. The catalytic decarbonylation of 2,4,5-trifluoro-benzaldehyde to 1,2,4-trifluorobenzene by CoMe(PMe3)4 was explored. A mechanism of the catalytic decarbonylation reaction was speculated with the support of experiment.72
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 439, 1 January 2016, Pages 100-105
Journal: Inorganica Chimica Acta - Volume 439, 1 January 2016, Pages 100-105
نویسندگان
Shuo Yuan, Hongjian Sun, Shumiao Zhang, Xiaoyan Li,