کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325888 | 1499944 | 2010 | 6 صفحه PDF | دانلود رایگان |
Quantum chemical studies of the reaction of selenium dichloride with divinyl sulfide have been carried out. The major reaction route (2,6-dichloro-1,4-thiaselenane → 5-chloro-2-chloromethyl-1,3-thiaselenolane → 2-chloromethyl-1,3-thiaselenole) and main trends of the reaction (a rearrangement of 2,6-dichloro-1,4-thiaselenane, facile selective dehydrochlorination of 5-chloro-2-chloromethyl-1,3-thiaselenolane), which have been determined by the quantum chemical studies, are in excellent agreement with experimental data.
Quantum chemical studies of the reaction of selenium dichloride with divinyl sulfide have been carried out. The major reaction route (2,6-dichloro-1,4-thiaselenane → 5-chloro-2-chloromethyl-1,3-thiaselenolane → 2-chloromethyl-1,3-thiaselenole) and main trends of the reaction (a rearrangement of 2,6-dichloro-1,4-thiaselenane, facile selective dehydrochlorination of 5-chloro-2-chloromethyl-1,3-thiaselenolane), which have been determined by the quantum chemical studies, are in excellent agreement with experimental data.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issues 10–11, 15 May 2010, Pages 1603–1608