کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328040 | 977529 | 2008 | 7 صفحه PDF | دانلود رایگان |
Stable pallada(II)cycles featuring Csp2–Pd and Csp3–Pd bonds reacted with vinyl- and alkynyl(phenyl)iodonium salts to generate two new geminal carbon–carbon bonds to the terminal carbon of the vinyl and alkynyl substituents providing benzofuran and dihydrobenzofuran heterocycles. The new annulation process was rationalized by the involvement of Pd(IV) intermediates arising via an initial oxidative addition of hypervalent iodonium electrophiles to the Pd(II) center. Reaction monitoring via low temperature 1H NMR spectroscopy was performed, and organopalladium(II) intermediates featuring a new Csp2–Csp2 or Csp2–Csp bond were isolated and characterized, providing insights into the regiochemical course of the proposed mechanistic pathway.
Stable pallada(II)cycles reacted with vinyl- and alkynyl(phenyl)iodonium salts to afford substituted benzofurans via a pathway presumed to involve transient Pd(IV) intermediates.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 3, 1 February 2008, Pages 567–573