کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328626 | 1499952 | 2005 | 5 صفحه PDF | دانلود رایگان |
Polymer-supported ruthenium-containing complex PS–Phen–Ru was synthesized (where PS = chloromethyl polystyrene resin, Phen = 1,10-phenanthroline) and was characterized by FT-IR, ICP, and XPS. The supported complex was used to catalyze the oxidation of primary aliphatic alcohols as well as aromatic alcohols in the presence of iodosylbenzene. The oxidations were carried out in acetonitrile solution, affording the corresponding aldehydes or ketones in high substrate conversion and high selectivities under mild reaction conditions. The catalyst can be easily prepared and can be recycled.
Catalytic oxidation of primary aliphatic alcohols and aromatic alcohols in the presence of iodosylbenzene (PhIO) by the polymer-supported ruthenium complex PS–Phen–Ru gives the corresponding aldehydes or ketones with high substrate conversion and selctivity.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 26, 15 December 2005, Pages 6309–6313