کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328650 | 977614 | 2005 | 13 صفحه PDF | دانلود رایگان |
A series of arylstannanes have been synthesized, through an SRN1 mechanism, in good to excellent yields (74%–99%) by the photostimulated reaction of trimethyl stannyl ion with substrates supporting different nucleofugal groups. The arylstannanes thus obtained were suitable intermediates for Stille cross-coupling reactions leading to asymmetric bi- and triaryl compounds in acceptable global yields. An attractive feature of this route is that simple commercially available benzenediols, chloro- and methoxy phenols might be useful starting substrates, leading the latter to higher global yields of products in fewer steps. The strategies proposed open a broad synthetic tool.
The photostimulated reaction of Me3SnNa with aryl substrates supporting different nucleofugal groups yielded the corresponding arylstannanes (74–99%) which, through Stille cross-coupling reactions, led to asymmetric bi- and triaryls in acceptable global yields. Commercially available benzenediols, chloro- and methoxy phenols might be useful starting substrates.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 17, 1 September 2005, Pages 3865–3877