Syntheses, structures and luminescent properties of a series of 3D lanthanide coordination polymers with tripodal semirigid ligand

Reactions of the tripodal bridging ligand 5-(4-carboxy–phenoxy)-isophthalic acid (abbreviated as H3cpia) with lanthanide salts lead to the formation of a family of different coordination polymers, that is, [Ln(cpia)(H2O)2]n·nH2O (Ln=Ce (1), Pr (2), Nd (3), Sm (4), Eu (5), Gd (6), Dy (7), Er (8), Tm (9) and Y (10)) in the presence of formic acid or diethylamine, which are characterized by elemental analysis, IR spectrum, thermogravimetric analysis (TGA), XRPD spectrum and single-crystal X-ray diffraction. Compounds 1–10 are isostructural and exhibit three-dimensional microporous frameworks. Furthermore, the photoluminescent properties of 4, 5 and 7 have been studied in detail.

Reactions of the tripodal bridging ligand (H3cpia) with lanthanide ions lead to the formation of a series of coordination polymers in the presence of formic acid or diethylamine.Figure optionsDownload as PowerPoint slideResearch Highlights
► Ten new lanthanides-based coordination polymers (1–10) have been synthesized.
► 1–10 exhibit 3D (4,8)-connected fluorite topology networks with 1D channel parallel to the b-axis.
► Compounds 4, 5 and 7 exhibit characteristic luminescence of Sm3+, Eu3+ and Dy3+ ions, respectively.