Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties

Two new 3D bismuth containing coordination polymers are reported along with their single crystal structures and SHG properties. Compound 1: Bi2O2(pydc) (pydc=pyridine-2, 5-dicarboxylate), crystallizes in the monoclinic, polar space group, P21 (a=9.6479(9) Å, b=4.2349(4) Å, c=11.9615(11) Å, β=109.587(1)°), which contains Bi2O2 chains that are connected into a 3D structure via the pydc ligands. Compound 2: Bi4Na4(1R3S-cam)8(EtOH)3.1(H2O)3.4 (1R3S cam=1R3S-camphoric acid) crystallizes in the monoclinic, polar space group, P21 (a=19.0855(7) Å, b=13.7706(5) Å, c=19.2429(7) Å, β=90.701(1)°) and is a true 3D coordination polymer. These are two example of SHG compounds prepared using unsymmetric ligands (compound 1) or chiral ligands (compound 2), together with metals that often exhibit stereochemically-active lone pairs, such as Bi3+, a synthetic approach that resulted in polar, non-centrosymmetric, 3D metal-organic coordination polymer.

Graphical AbstractStructures of two new, polar, 3D Bismuth(III)-based coordination polymers: Bi2O2(pydc) (compound 1), and Bi4Na4(1R3S-cam)8(EtOH)3.1(H2O)3.4 (compound 2).Figure optionsDownload as PowerPoint slideHighlights
► New, polar, 3D Bismuth(III)-based coordination polymers.
► First polar bismuth-based coordination polymers synthesized via a “hybrid” strategy.
► Combination of stereochemically-active lone pairs and unsymmetrical or chiral ligands.
► Synthesis of class C-SHG materials based on Kurtz–Perry categories.