کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1331947 | 979025 | 2006 | 10 صفحه PDF | دانلود رایگان |
Additional X-ray diffraction effects yielding an eightfold commensurate superstructure [a=20.974(5)Å] of the ideal pyrochlore structure were observed after annealing at 873 K of a thallium-doped bariopyrochlore single crystal. Electron diffraction indicated the coexistence of two cubic phases, the pyrochlore structure and a new F -centred, cubic phase. The superstructure was solved and refined in the space group F4¯3m. The two phases were combined together and refined as independently diffracting to R=0.0628R=0.0628. The resulting unit-cell content is (A,□)20Nb16Ti2O53(Z=8)(Z=8), with A=Ba, Tl, Ce, Th. For some atomic positions of the superstructure, third- and fourth-order anharmonic ADP's were used to account for the specific density shape having a continuous character as typical for ionic conductors. There are three distinct clusters in the superstructure, leading to a new structure type no longer strictly of pyrochlore-structure type.
We report a new structure type related to that of pyrochlore containing three distinct types of corner-connected clusters, each made up of four individual BO6 octahedra—the original tetrahedra of octahedra characteristic of the ideal pyrochlore-structure type, an ‘opened out’ version of this cluster and clusters of four TiO6 octahedra forming small units of the NaCl structure type.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 3, March 2006, Pages 729–738