Preparation, crystal structure, and photoluminescence of Ca2SnO4:Eu3+, Y3+

Eu3+-doped Ca2SnO4 (solid solutions of Ca2−xEu2xSn1−xO4, 0⩽x⩽0.3) and Eu3+ and Y3+-codoped Ca2SnO4 (Ca1.8Y0.2Eu0.2Sn0.8O4) were prepared by solid-state reaction at 1400 °C in air. Rietveld analysis of the X-ray powder diffraction patterns revealed that Eu3+ replaced Ca2+ and Sn4+ in Eu3+-doped Ca2SnO4, and that Eu3+ replaced Ca2+ and Y3+ replaced Sn4+ in Ca1.8Y0.2Eu0.2Sn0.8O4. Red luminescence at 616 nm due to the electric dipole transition 5Do→7F2 was observed in the photoluminescence (PL) spectra of Ca2−xEu2xSn1−xO4 and Ca1.8Y0.2Eu0.2Sn0.8O4 at room temperature. The maximum PL intensity in the solid solutions of Ca2−xEu2xSn1−xO4 was obtained for x=0.1. The PL intensity of Ca1.8Y0.2Eu0.2Sn0.8O4 was 1.26 times greater than that of Ca2−xEu2xSn1−xO4 with x=0.1.

Rietveld analysis of the X-ray powder diffraction patterns revealed that Eu3+ replaced Ca2+ and Sn4+ in Ca2−xEu2xSn1−xO4, (0⩽x⩽0.3), and Eu3+ replaced Ca2+ and Y3+ replaced Sn4+ in Ca1.8Y0.2Eu0.2Sn0.8O4. Red luminescence at 616 nm due to the 5Do→7F2 transition was observed in the photoluminescence spectra of these compounds.Figure optionsDownload as PowerPoint slide