کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1332398 | 1500115 | 2013 | 5 صفحه PDF | دانلود رایگان |
Single crystals of the osmium-containing compound Ca3OsO6 have been successfully grown under high-pressure conditions, for the first time. The crystal structure of Ca3OsO6 were characterized as an ordered double-perovskite structure of space group P21/n with the Ca and Os atoms being fully ordered at the perovskite B-site. The electromagnetic analysis shows that the crystal exhibits a semiconductor-like behavior below 300 K and undergoes an antiferromagnetic transition at 50 K.
Graphical AbstractSchematic image of crystal structure of Ca3OsO6 as determined by X-ray diffraction, where the gray and black octahedrons are occupied by Ca and Os, respectively. Top inset reveals an optic image of a typical Ca3OsO6 single crystal.Figure optionsDownload as PowerPoint slideHighlights
► Single crystals of Ca3OsO6 have been successfully grown under high-pressure.
► Ca3OsO6 crystalizes into an ordered double-perovskite structure.
► The Ca3OsO6 undergoes an antiferromagnetic transition at 50 K.
Journal: Journal of Solid State Chemistry - Volume 201, May 2013, Pages 186–190