کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1332437 979042 2012 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cu(N–N)2Cl2 and Cu(N–N–N)Cl2 and HgCl2 building blocks in the synthesis of coordination compounds—X-ray studies and magnetic properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Cu(N–N)2Cl2 and Cu(N–N–N)Cl2 and HgCl2 building blocks in the synthesis of coordination compounds—X-ray studies and magnetic properties
چکیده انگلیسی

A series of complexes containing Cu(N–N)2Cl2 (N–N=bis(pyrazol-1-yl)methane (bpzm), bis(3,5dimethylpyrazol-1-yl)methane (bdmpzm), 2,2-dipyridylamine (dpa), 5,6-diphenyl-3-(2-pyridyl)-1,2,4-trazine (dppt) and 2,2′-bipyridine (bipy)), Cu(N–N–N)Cl2 (N–N–N=2,2′:6′,2″-terpyridine (terpy)) and HgCl2 building blocks have been synthesized and structurally characterized. Increase in structural dimensionality is observed for [Cu(bpzm)2][HgCl4], [Cu(dpa)2][HgCl3]2 and [Cu(terpy)(μ-Cl)HgCl3] compounds. No coordination polymers have formed in the case of bis(3,5dimethylpyrazol-1-yl)methane, 5,6-diphenyl-3-(2-pyridyl)-1,2,4-trazine and 2,2′-bipyridine. The [Cu(bpzm)2][HgCl4] and [Cu(terpy)(μ-Cl)HgCl3] complexes have been studied by magnetic measurements.

N–N: bis(3,5dimethylpyrazol-1-yl)methane (bdmpzm), 2,2-dipyridylamine (dpa), 5,6-diphenyl-3-(2-pyridyl)-1,2,4-trazine (dppt) and 2,2′-bipyridine (bipy), 6′,2″-terpyridine (terpy).Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 183, Issue 9, September 2010, Pages 2012–2020
نویسندگان
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