کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1332732 | 979052 | 2008 | 4 صفحه PDF | دانلود رایگان |
FeVO4 (I) single crystals are grown by the flux method using V2O5 as the self-flux. The grown crystals exhibit a characteristic morphology with natural facets. The quality of the crystals is confirmed by X-ray diffraction and EPMA techniques. Magnetic properties are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. Two magnetic phase transitions are observed at ∼13 and ∼20 K. Such unusual magnetic behaviors are suggested to originate from two different Fe ligand environments of octahedral FeO6 and trigonal bipyramidal FeO5 in a six-column doubly bent chain.
FeVO4 (I) single crystals are grown by the flux method using V2O5 as the self-flux. Magnetic properties are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements, showing two magnetic phase transitions at ∼13 and ∼20 K.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 181, Issue 9, September 2008, Pages 2346–2349