Synthesis, structure and magnetic properties of new phosphates K2Mn0.5Ti1.5(PO4)3 and K2Co0.5Ti1.5(PO4)3 with the langbeinite structure

New complex phosphates of the general formula K2M0.5Ti1.5(PO4)3 (M=Mn, Co) have been obtained from the melting mixture of KPO3, K4P2O7, TiO2 and CoCO3·mCo(OH)2 or Mn(H2PO4)2 by means of a flux technique. The synthesized phosphates have been characterized by the single-crystal X-ray diffraction and the FTIR-spectroscopy. The compounds crystallize in the cubic system with the space group P213 and cell parameters a=9.9030(14) Å for K2Mn0.5Ti1.5(PO4)3 and a=9.8445(12) Å for K2Co0.5Ti1.5(PO4)3. Both phosphates are isostructural with the langbeinite mineral and contain four formula unit K2M0.5Ti1.5(PO4)3 per unit cell. The structure can be described using [M2(PO4)3] framework composed of two [MO6] octahedra interlinked via three [PO4] tetrahedra. The Curie–Weiss-type behavior is observed in the magnetic susceptibility.

A view of langbeinite structure in direction perpendicular to [111].Figure optionsDownload as PowerPoint slide